Olá amigo, faça o seguinte.
Declare a constante a function:
Public Const SW_SHOW As Long = 5
Declare Function ShellExecute Lib "shell32.dll" Alias _
"ShellExecuteA" ( ByVal hwnd As Long, ByVal _
lpOperation As String, ByVal lpFile As String, _
ByVal lpParameters As String, ByVal lpDirectory _
As String, ByVal nShowCmd As Long) As Long
Depois, no evento chame a ShellExecute.
Private Sub Button_Click()
dim i&
i& = ShellExecute(0,"open",[arquivo ex: c:meuarq.doc],"","",SW_SHOW)
End Sub
Espero ter ajudado.
Att.